Glucosylimidazolium Hydroxide: A Bench-Stable Carbohydrate Based Building Block
نویسندگان
چکیده
Hygroscopic effects in ionic liquids and salts general, how to suppress said hygroscopy, often needs be considered during the everyday work routine. Chemicals that decompose, undergo hydrolysis or any way change their composition when exposed air are generally not bench-stable. In this study, we synthesized a low-hygroscopic, bench-stable carbohydrate-based hydroxide salt. This new product was an optimized three-step procedure with 91% overall yield. Its worth as building block proven through reaction different natural acids, leading (CHILs) process.
منابع مشابه
Al12Cu Superatom as Stable Building Block of Ionic Salts
The neutral copper aluminum cluster complex Al12CuM3 [M = K, K3O, and K(2,2,2-crypt)] has been investigated at the PBE96 level of theory. It is found that Al12Cu could be considered a superatom mimic of a phosphorus atom. It shows large electron affinity and is able to receive three electrons from elements or compounds with low ionization energies like K, K3O, or K(2,2,2-crypt) to become a stab...
متن کاملA building block placement tool
based approach for placement [2][3]. Onodera describes a branch and bound based placement approach [4]. Sechen’s TimberwolfMC placement and global routing tool was one of the first tools based on simulated annealing [5]. Lastly, one of the most recent proposals to placement was a rectangle packing approach described by Kajitani [6]. Each method has its merits, but so far, no method has emerged ...
متن کاملA Competitive Building Block Hypothesis
This paper is concerned with examining the way in which rooted building blocks grow in GP-like systems. We hypothesize that, in addition to the normal notion of co-operative building blocks, there are also competitive building blocks in the population. These competitive building blocks are all of the rooted variety, all share a similar root structure and compete with each other to spread their ...
متن کاملRelative Building-Block Fitness and the Building Block Hypothesis
The building-block hypothesis states that the GA works well when short, low-order, highly-fit schemas recombine to form even more highly fit higher-order schemas. The ability to produce fitter and fitter partial solutions by combining building blocks is believed to be a primary source of the GA’s search power, but the GA research community currently lacks precise and quantitative descriptions o...
متن کاملNew Blatter-type radicals from a bench-stable carbene
Stable benzotriazinyl radicals (Blatter's radicals) recently attracted considerable interest as building blocks for functional materials. The existing strategies to derivatize Blatter's radicals are limited, however, and synthetic routes are complex. Here, we report that an inexpensive, commercially available, analytical reagent Nitron undergoes a previously unrecognized transformation in wet a...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Compounds
سال: 2021
ISSN: ['2673-6918']
DOI: https://doi.org/10.3390/compounds1030014